2025
(35) Sorvanov, A.; Deolka, S.; Khaskin, E.; Fayzullin, R. R.; Vasylevskyi, S.; Khusnutdinova, J. Self-Assembly of a Customizable Library of Nickel Trifluoromethylation Catalysts via Selective C‒F and C‒O Bond Cleavage. Angew Chem Int Ed Engl 2025, e202509042.
(34) Marae, I. S.; Tan, J.; Yoshioka, R.; Ziadi, Z.; Khaskin, E.; Vasylevskyi, S.; Kabe, R.; Xu, X.; Narita, A. Synthesis and characterizations of highly luminescent 5-isopropoxybenzo[rst]pentaphene. Beilstein J. Org. Chem. 2025, 21, 270-276.
2024
(33) Moradi, H.; Govindarajan, R.; Nguyen, H. G.; Deolka, S.; Dinh, H. M.; Khaskin, E.; Fayzullin, R. R.; Vasylevskyi, S.; Khusnutdinova, J. R. Synthesis and Aerobic Oxidation of Perfluoroalkyl d10 Metal Complexes Supported by 2,7-Dimethyl-1,8-Naphthyridine. Eur. J. Inorg. Chem. 2024, 27 (23), e202400257.
(32) Haaheim, K. S.; Deolka, S.; Fayzullin, R. R.; Lund, B. A.; Khaskin, E.; Sydnes, M. O. 2-Pyridinyl/quinolyl-phenylamino-quinoline Complexes With CF3 and C2F5 Ligated Ni. Eur. J. Inorg. Chem. 2024, 27 (25), e202400207.
(31) Govindarajan, R.; Vardhanapu, P. K.; Fayzullin, R. R.; Khaskin, E.; Khusnutdinova, J. R. Facile methyl group transfer from PtII to gallium and indium. Chem. Commun. (Cambridge, U. K.) 2024, 60 (56), 7216-7219.
(30) Govindarajan, R.; Fayzullin, R. R.; Deolka, S.; Khaskin, E.; Vasylevskyi, S.; Vardhanapu, P. K.; Pal, S.; Khusnutdinova, J. R. Facile Access to Cationic Methylstannylenes and Silylenes Stabilized by E-Pt Bonding and their Methyl Group Transfer Reactivity. Chem. - Eur. J. 2024, 30 (8), e202303789.
2023
(29) Pandey, D. K.; Khaskin, E.; Pal, S.; Fayzullin, R. R.; Khusnutdinova, J. R. Efficient Fe-Catalyzed Terminal Alkyne Semihydrogenation by H2: Selectivity Control via a Bulky PNP Pincer Ligand. ACS Catal. 2023, 13 (1), 375-381.
(28) Pandey, D. K.; Khaskin, E.; Khusnutdinova, J. R. PNP-Pincer Ligands Armed With Methyls: New Tools To Control Sterics and Non-Innocence. ChemCatChem 2023, 15 (20), e202300644.
(27) Dinh, H. M.; He, Y.-T.; Fayzullin, R. R.; Vasylevskyi, S.; Khaskin, E.; Khusnutdinova, J. R. Synthesis of Aryl-Manganese(III) Fluoride Complexes via α-Fluorine Elimination from CF3 and Difluorocarbene Generation. Eur. J. Inorg. Chem. 2023, 26 (32), e202300460.
(26) Dinh, H. M.; Govindarajan, R.; Deolka, S.; Fayzullin, R. R.; Vasylevskyi, S.; Khaskin, E.; Khusnutdinova, J. R. Photoinduced Perfluoroalkylation Mediated by Cobalt Complexes Supported by Naphthyridine Ligands. Organometallics 2023, 42 (18), 2632-2643.
(25) Deolka, S.; Govindarajan, R.; Khaskin, E.; Vasylevskyi, S.; Bahri, J.; Fayzullin, R. R.; Roy, M. C.; Khusnutdinova, J. R. Oxygen transfer reactivity mediated by nickel perfluoroalkyl complexes using molecular oxygen as a terminal oxidant. Chem. Sci. 2023, 14 (25), 7026-7035.
(24) Deolka, S.; Govindarajan, R.; Gridneva, T.; Roy, M. C.; Vasylevskyi, S.; Vardhanapu, P. K.; Khusnutdinova, J. R.; Khaskin, E. General High-Valent Nickel Metallocycle Catalyst for the Perfluoroalkylation of Heteroarenes and Peptides. ACS Catal. 2023, 13 (19), 13127-13139.
(23) Bahri, J.; Deolka, S.; Vardhanapu, P. K.; Khaskin, E.; Govindarajan, R.; Fayzullin, R. R.; Vasylevskyi, S.; Khusnutdinova, J. R. Photoinduced Carbon-Heteroatom Cross-Coupling Catalyzed by Nickel Naphthyridine Complexes. ChemCatChem 2023, 15 (24), e202301142.
2022
(22) Karimata, A.; Gridneva, T.; Patil, P. H.; Fayzullin, R. R.; Khaskin, E.; Lapointe, S.; Garcia-Roca, A.; Khusnutdinova, J. R. Ethylene binding in mono- and binuclear CuI complexes with tetradentate pyridinophane ligands. Dalton Trans. 2022, 51 (35), 13426-13434.
(21) Govindarajan, R.; Deolka, S.; Khaskin, E.; Fayzullin, R. R.; Pal, S.; Vasylevskyi, S.; Khusnutdinova, J. R. H2, B-H, and Si-H Bond Activation and Facile Protonolysis Driven by Pt-Base Metal Cooperation. Chem. - Eur. J. 2022, 28 (44), e202201639.
(20) Dinh, H. M.; Gridneva, T.; Karimata, A.; Garcia-Roca, A.; Pruchyathamkorn, J.; Patil, P. H.; Petrov, A.; Sarbajna, A.; Lapointe, S.; Khaskin, E.; et al. Single and double deprotonation/dearomatization of the N,S-donor pyridinophane ligand in ruthenium complexes. Dalton Trans. 2022, 51 (38), 14734-14746.
(19) Deolka, S.; Govindarajan, R.; Vasylevskyi, S.; Roy, M. C.; Khusnutdinova, J. R.; Khaskin, E. Ligand-free nickel catalyzed perfluoroalkylation of arenes and heteroarenes. Chem. Sci. 2022, 13 (44), 12971-12979.
(18) Deolka, S.; Fayzullin, R. R.; Khaskin, E. Bulky PNP Ligands Blocking Metal-Ligand Cooperation Allow for Isolation of Ru(0), and Lead to Catalytically Active Ru Complexes in Acceptorless Alcohol Dehydrogenation. Chem. - Eur. J. 2022, 28 (4), e202103778.
2021
(17) Rivada-Wheelaghan, O.; Deolka, S.; Govindarajan, R.; Khaskin, E.; Fayzullin, R. R.; Pal, S.; Khusnutdinova, J. R. Construction of modular Pd/Cu multimetallic chains via ligand- and anion-controlled metal-metal interactions. Chem. Commun. (Cambridge, U. K.) 2021, 57 (79), 10206-10209.
(16) Lapointe, S.; Pandey, D. K.; Gallagher, J. M.; Osborne, J.; Fayzullin, R. R.; Khaskin, E.; Khusnutdinova, J. R. Cobalt Complexes of Bulky PNP Ligand: H2 Activation and Catalytic Two-Electron Reactivity in Hydrogenation of Alkenes and Alkynes. Organometallics 2021, 40 (21), 3617-3626.
(15) He, Y.-T.; Karimata, A.; Gladkovskaya, O.; Khaskin, E.; Fayzullin, R. R.; Sarbajna, A.; Khusnutdinova, J. R. C-C Bond Elimination from High-Valent Mn Aryl Complexes. Organometallics 2021, 40 (14), 2320-2331.
(14) Deolka, S.; Govindarajan, R.; Khaskin, E.; Fayzullin, R. R.; Roy, M. C.; Khusnutdinova, J. R. Photoinduced Trifluoromethylation of Arenes and Heteroarenes Catalyzed by High-Valent Nickel Complexes. Angew. Chem., Int. Ed. 2021, 60 (46), 24620-24629.
2020
(13) Vojkovsky, T.; Deolka, S.; Stepanova, S.; Roy, M. C.; Khaskin, E. Catalytic Sulfone Upgrading Reaction with Alcohols via Ru(II). ACS Catal. 2020, 10 (12), 6810-6815.
(12) Karimata, A.; Patil, P. H.; Khaskin, E.; Lapointe, S.; Fayzullin, R. R.; Stampoulis, P.; Khusnutdinova, J. R. Highly sensitive mechano-controlled luminescence in polymer films modified by dynamic CuI-based cross-linkers. Chem. Commun. (Cambridge, U. K.) 2020, 56 (1), 50-53.
(11) Karimata, A.; Patil, P. H.; Fayzullin, R. R.; Khaskin, E.; Lapointe, S.; Khusnutdinova, J. R. Triboluminescence of a new family of CuI-NHC complexes in crystalline solid and in amorphous polymer films. Chem. Sci. 2020, 11 (39), 10814-10820.
(10) Deolka, S.; Rivada-Wheelaghan, O.; Aristizabal, S. L.; Fayzullin, R. R.; Pal, S.; Nozaki, K.; Khaskin, E.; Khusnutdinova, J. R. Metal-metal cooperative bond activation by heterobimetallic alkyl, aryl, and acetylide PtII/CuI complexes. Chem. Sci. 2020, 11 (21), 5494-5502.
(9) Dawe, L. N.; Karimzadeh-Younjali, M.; Dai, Z.; Khaskin, E.; Gusev, D. G. The Milstein Bipyridyl PNN Pincer Complex of Ruthenium Becomes a Noyori-Type Catalyst under Reducing Conditions. J. Am. Chem. Soc. 2020, 142 (46), 19510-19522.
(8) Dalphin, N.; Dorgans, K.; Khaskin, E.; Kuhn, B. Voltage Imaging of Cortical Oscillations in Layer 1 with Two-Photon Microscopy. eNeuro 2020, 7 (3).
2019
(7) Sarbajna, A.; Patil, P. H.; Dinh, M. H.; Gladkovskaya, O.; Fayzullin, R. R.; Lapointe, S.; Khaskin, E.; Khusnutdinova, J. R. Facile and reversible double dearomatization of pyridines in non-phosphine Mn(I) complexes with N,S-donor pyridinophane ligand. Chem. Commun. (Cambridge, U. K.) 2019, 55 (22), 3282-3285.
(6) Sarbajna, A.; He, Y.-T.; Dinh, M. H.; Gladkovskaya, O.; Rahaman, S. M. W.; Karimata, A.; Khaskin, E.; Lapointe, S.; Fayzullin, R. R.; Khusnutdinova, J. R. Aryl-X Bond-Forming Reductive Elimination from High-Valent Mn-Aryl Complexes. Organometallics 2019, 38 (22), 4409-4419.
(5) Lapointe, S.; Khaskin, E.; Fayzullin, R. R.; Khusnutdinova, J. R. Stable Nickel(I) Complexes with Electron-Rich, Sterically-Hindered, Innocent PNP Pincer Ligands. Organometallics 2019, 38 (7), 1581-1594.
(4) Lapointe, S.; Khaskin, E.; Fayzullin, R. R.; Khusnutdinova, J. R. Nickel(II) Complexes with Electron-Rich, Sterically Hindered PNP Pincer Ligands Enable Uncommon Modes of Ligand Dearomatization. Organometallics 2019, 38 (22), 4433-4447.
(3) Deolka, S.; Tarannam, N.; Fayzullin, R. R.; Kozuch, S.; Khaskin, E. Unusual rearrangement of modified PNP ligand based Ru complexes relevant to alcohol dehydrogenation catalysis. Chem. Commun. (Cambridge, U. K.) 2019, 55 (76), 11350-11353.
2018
(2) Jankins, T. C.; Fayzullin, R. R.; Khaskin, E. Three-Component [1 + 1 + 1] Cyclopropanation with Ruthenium(II). Organometallics 2018, 37 (15), 2609-2617.
2016
(1) Dubey, A.; Khaskin, E. Catalytic Ester Metathesis Reaction and Its Application to Transfer Hydrogenation of Esters. ACS Catal. 2016, 6 (6), 3998-4002.
2015
Postdoc 6: Khaskin, E.; Milstein, D. Catalytic, oxidant-free, direct olefination of alcohols using Wittig reagents. Chem. Commun. (Cambridge, U. K.) 2015, 51 (43), 9002-9005.
Postdoc 5: Khaskin, E.; Fadida, T.; Kroupitski, Y.; Shemesh, M.; Cristaldi, D. A.; Gulino, A.; Poverenov, E. A contact active bactericidal stainless steel via a sustainable process utilizing electrodeposition and covalent attachment in water. Green Chem. 2015, 17 (4), 2344-2347.
2013
Postdoc 4: Khaskin, E.; Milstein, D. Simple and Efficient Catalytic Reaction for the Selective Deuteration of Alcohols. ACS Catal. 2013, 3 (3), 448-452.
Postdoc 3: Khaskin, E.; Diskin-Posner, Y.; Weiner, L.; Leitus, G.; Milstein, D. Formal loss of an H radical by a cobalt complex via metal-ligand cooperation. Chem. Commun. (Cambridge, U. K.) 2013, 49 (27), 2771-2773.
Postdoc 2: Balaraman*, E.; Khaskin, E.*; Leitus, G.; Milstein, D. Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source. Nat. Chem. 2013, 5 (2), 122-125. *-First co-authors
2010
Grad School 6: Oloo, W.; Zavalij, P. Y.; Zhang, J.; Khaskin, E.; Vedernikov, A. N. Preparation and C-X Reductive Elimination Reactivity of Monoaryl PdIV-X Complexes in Water (X = OH, OH2, Cl, Br). J. Am. Chem. Soc. 2010, 132 (41), 14400-14402.
Postdoc 1: Khaskin, E.; Iron, M. A.; Shimon, L. J. W.; Zhang, J.; Milstein, D. N-H Activation of Amines and Ammonia by Ru via Metal-Ligand Cooperation. J. Am. Chem. Soc. 2010, 132 (25), 8542-8543.
2009
Grad School 5: Khaskin, E.; Lew, D. L.; Pal, S.; Vedernikov, A. N. Homogeneous catalytic transfer dehydrogenation of alkanes with a group 10 metal center. Chem. Commun. (Cambridge, U. K.) 2009, (41), 6270-6272.
2008
Grad School 4: Zhang, J.; Khaskin, E.; Anderson, N. P.; Zavalij, P. Y.; Vedernikov, A. N. Catalytic aerobic oxidation of substituted 8-methylquinolines in PdII-2,6-pyridinedicarboxylic acid systems. Chem. Commun. (Cambridge, U. K.) 2008, (31), 3625-3627.
Grad School 3: Khaskin, E.; Zavalij, P. Y.; Vedernikov, A. N. Bidirectional Transfer of Phenyl and Methyl Groups between PtIV and Boron in Platinum Dipyridylborato Complexes. J. Am. Chem. Soc. 2008, 130 (31), 10088-10089.
2007
Grad School 2: Khaskin, E.; Zavalij, P. Y.; Vedernikov, A. N. Oxidatively induced methyl transfer from boron to platinum in dimethyldi(2-pyridyl)boratoplatinum complexes. Angew. Chem., Int. Ed. 2007, 46 (33), 6309-6312.
2006
Grad School 1: Khaskin, E.; Zavalij, P. Y.; Vedernikov, A. N. Facile Arene C-H Bond Activation and Alkane Dehydrogenation with Anionic LPtIIMe2- in Hydrocarbon-Water Systems (L = Dimethyldi(2-pyridyl)borate). J. Am. Chem. Soc. 2006, 128 (40), 13054-13055.